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Assignment 3, MSE 362

Due Date: 05-22-2023 (beginning of lecture)

Viscoelastic response of a polymer is fitted at 100 ℃ using a generalized Maxwell model with 12 elements and G∞  = 250 MPa:

Element i

Gi/G

λ i  (s)

1

0.004

1.00E-06

2

0.020

1.00E-05

3

0.040

1.00E-04

4

0.060

1.00E-03

5

0.080

1.00E-02

6

0.110

1.00E-01

7

0.130

1.00E+00

8

0.150

1.00E+01

9

0.130

1.00E+02

10

0.100

1.00E+03

11

0.020

1.00E+04

12

0.004

1.00E+05

-      Calculate and show the relaxation modulus using elements (1,4,8,12) only.

-      Calculate and show the relaxation modulus using even elements only (2,4,6,8,10,12) .

-      Calculate and show the relaxation modulus using all 12 elements.

-      Compare previous results and comment on their differences. What are the glassy and rubbery modulus of the material?

-     Assume that the constants of the WLF equation for this polymer are given as below:

C1  = 20, C2  = 50 (℃)

calculate and show the relaxation modulus of the material using all 12 elements at three temperatures of 95 ℃, 100 ℃ and 115 ℃ . Based on these results, how long it takes for the relaxation modulus to reach 350 MPa at 95 ℃, 100 ℃ and 115 ℃?